مختصر البحث:
In this research, Zn/ZnO Nanoparticles (NPs) were prepared via
the Pulse Laser Ablation (PLA) method using three liquids (Ethanol,
Acetone, and Distilled Water). Zn/ZnO NPs were synthesized via an
Nd-YAG laser with a wavelength of 1064 nm, applie…
In this research, Zn/ZnO Nanoparticles (NPs) were prepared via
the Pulse Laser Ablation (PLA) method using three liquids (Ethanol,
Acetone, and Distilled Water). Zn/ZnO NPs were synthesized via an
Nd-YAG laser with a wavelength of 1064 nm, applied energy of 800
mJ, a frequency of 6 Hz, and 100 laser pulses at room temperature. The
Zn metal plate was dipped in Ethanol, Acetone, and Distilled Water,
respectively. The UV-Vis results shows sharp and single peaks at 320,
341, and 333 nm for Zn/ZnO NPs in Ethanol, Acetone, and Distilled
Water respectively. FTIR testing shows peaks at about 500 cm−1 for
Zn/ZnO NPs in Ethanol, Acetone, and Distilled Water, which indicates
Zn-O stretching vibrations. XRD investigation shows low-angle peaks
at 23.31˚, 23.81˚, and 19.20˚ for Zn/ZnO NPs in Ethanol, Acetone, and
Distilled Water, respectively. In addition, a sharp peak of high intensity
was observed at 13.54˚ for Zn/ZnO Core/Shell NPs in Acetone. These
peaks indicate that the structure is stable and undistorted. These patterns
emphasize compact pore arrangements. The lower intensity of the
gradient peaks indicates that ZnO formed at a preferred site. Nor did
high-angle XRD patterns appear, indicating that the formed ZnO NPs
are so small to be distinct from background noise or undetectable by
widish angle XRD. The broad XRD peak at 2θ angles from 20° to 30°
can also confirm that ZnO is low-crystalline. The TEM images show the
presence of Zn/ZnO NPs in Ethanol, Acetone, and Distilled Water with
a size of less than 50 nm, and TEM analysis confirms that the primary
structure of Zn/ZnO NPs is a Core/Shell.
